Radical-triggered translocation of C–C double bond and functional group Shengchun Wang Xu Luo Aiwen Lei Nature Chemistry (2024) Nickel-catalyzed arylcyanation of alkenes via cyano group translocation: access to 1,n-dinitriles or 4-amino nitriles Xiaohong Li Shenfan Wang Liangbin Huang ...
double bond, or a mixture of said compound [1] and [2] at least one compound selected from the group consisting of ethylenically unsaturated compounds having a carbon-to-carbon double bond and neither unsaturation at the position conjugate to said double bond nor a functional group, with a ...
To find the stable binding conformation of Pt3 that potential can form dual crosslinking bond to G2 and G19 simultaneously, the distance constraint with the value of 5.0/Å2 was applied between Pt center and N7 of G2, and between the second Pt(II) and N7 of G19. The minimum ...
This communication demonstrates the first catalytic aminoboration of C–C π bonds by B–N σ bonds and its application to the synthesis of 3-borylated indoles. The regiochemistry and broad functional group compatibility of this addition reaction enable substitution patterns that are incompatible with...
- 《Organometallics》 被引量: 2发表: 2007年 OXIDATIVE CLEAVAGE OF UNSATURATED CARBOXYLIC ACIDS Provided are processes for the oxidative cleavage of a double bond in an unsaturated carboxylic acid. The process includes contacting the unsaturated carbo... RG Blair 被引量: 0发表: 2012年 加载更多...
Selective hydrogenation of the C[double bond, length as m-dash]C bond in α,β-unsaturated aldehydes and ketones over ultra-small Pd-Au clusters Pd-Au clusters of 1.8 nm preferentially catalyzed the hydrogenation of the C[double bond, length as m-dash]C bond in α,β-unsaturated aldehydes...
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The catalytic reaction possibly via a double C-H bond activation process provided an efficient method for the synthesis of isoquinolones. Key words: Rh(III)-Catalyzed; C-H bond activation; Cyclization ;Heterocyclic compounds II 万方数据 目录 目录 第一章 前言 1 第一节 研究背景1 第二节 Rh(...
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Nevertheless, by combining structural characterization using cryo-EM with biochemical characterization and MD simulations, the CalA3 KS-catalyzed C–N bond formation and chain release improved our understanding of functional divergence of apparent KS domains. Considering that the LD-AT-DH-ψKR/KR ...